La bournonita es un mineral de origen hidrotermal, formado en condiciones de temperatura baja o media, lo que hace que aparezca asociado a otros minerales como la tetraedrita, la boulangerita o la siderita. Es un sulfuro, de fórmula química PbCuSbS3. La bournonita se descubrió en 1805 en Cornualles, en unas minas de la localidad de Endellion. Por esta razón fue llamada al principio «endelliolita» antes de que recibiera el nombre de bournonita en honor del mineralogista y cristalógrafo francés Jacques Louis Bournon.

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Bournonite is a sulfosalt mineral species, trithioantimoniate of lead and copper with the formula PbCuSbS3. It was first mentioned by Philip Rashleigh in 1797 as an ore of antimony and was more completely described in 1804 by French crystallographer and mineralogist Jacques Louis, Comte de Bournon (1751–1825), after whom it was named. The name given by Bournon himself (in 1813) was endellione, since used in the form endellionite, after the locality in Cornwall where the mineral was first found. The crystals are orthorhombic, and are generally tabular in habit owing to the predominance of the basal pinacoid; numerous smooth bright faces are often developed on the edges and corners of the crystals. They are usually twinned, the twin-plane being a face of the prism (m); the angle between the faces of this prism being nearly a right angle (86° 20′), the twinning gives rise to cruciform groups and when it is often repeated the group has the appearance of a cog-wheel, hence the name Rãdelerz (wheel-ore) of the Kapnik miners. The repeated twinning gives rise to twin-lamellae, which may be detected on the fractured surfaces, even of the massive material. It is a mineral in medium temperature hydrothermal vein deposits. It commonly occurs with galena, tetrahedrite, sphalerite, chalcopyrite, pyrite, stibnite, zinkenite, siderite, quartz, rhodochrosite, dolomite and barite. It was first described for an occurrence in Wheal Boys in the parish of St Endellion in Cornwall, it was found associated with jamesonite, sphalerite and siderite. Later, still better crystals were found in another Cornish mine, namely, Herodsfoot mine near Liskeard, which was worked for argentiferous galena. Fine crystals of large size have been found with quartz and siderite in the mines at Neudorf in the Harz, and with sphalerite and tetrahedrite at Cavnic near Baia Mare in Romania. It has been reported from a large number of other localities.

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