Los terpenos e isoprenoides son una vasta y diversa clase de compuestos orgánicos derivados del isopreno (o 2-metilbuta-1,3-dieno), un hidrocarburo de 5 átomos de carbono.Tradicionalmente se han considerado derivadas del 2-metil-butadieno más conocido como isopreno.Esta llamada «regla del isopreno» ha permitido clasificarlos y estudiarlos, pero realmente losterpenos no derivan del isopreno ya que éste nunca se ha encontrado como producto natural. Elverdadero precursor de los terpenos es el ácido mevalónico, el cual proviene del acetil coenzima A. El nombre proviene de que los primeros miembros de esta clase fueron derivados del aguarrás ("turpentine" en inglés, "terpentin" en alemán). Cuando los terpenos son modificados químicamente, por ejemplo por oxidación o reorganización del esqueleto hidrocarbonado, suelen denominarse terpenoides (como la vitamina A o retinol, que contiene un átomo de oxígeno). Los terpenos son el principal constituyente de los aceites esenciales de algunas plantas y flores, como el limonero, el naranjo.

Leer el artículo completo en Wikipedia · CC-BY-SA

Terpenes (/ˈtɜːrpiːn/) are a large and diverse class of organic compounds, produced by a variety of plants, particularly conifers, though also by some insects such as termites or swallowtail butterflies, which emit terpenes from their osmeteria. They often have a strong odor. They may protect the plants that produce them by deterring herbivores and by attracting predators and parasites of herbivores. Many terpenes are aromatic hydrocarbons and thus may have had a protective function. The difference between terpenes and terpenoids is that terpenes are hydrocarbons, whereas terpenoids contain additional functional groups. They are the major components of resin, and of turpentine produced from resin. The name "terpene" is derived from the word "turpentine". In addition to their roles as end-products in many organisms, terpenes are major biosynthetic building blocks within nearly every living creature. Steroids, for example, are derivatives of the triterpene squalene. When terpenes are modified chemically, such as by oxidation or rearrangement of the carbon skeleton, the resulting compounds are generally referred to as terpenoids. Some authors will use the term terpene to include all terpenoids. Terpenoids are also known as isoprenoids. Terpenes and terpenoids are the primary constituents of the essential oils of many types of plants and flowers. Essential oils are used widely as fragrances in perfumery, and in medicine and alternative medicines such as aromatherapy. Synthetic variations and derivatives of natural terpenes and terpenoids also greatly expand the variety of aromas used in perfumery and flavors used in food additives. Vitamin A is a terpene. Terpenes are released by trees more actively in warmer weather, acting as a natural form of cloud seeding. The clouds reflect sunlight, allowing the forest to regulate its temperature. The aroma and flavor of hops, highly desirable in some beers, comes from terpenes. Of the terpenes in hops myrcene, β-pinene, β-caryophyllene, and α-humulene are found in the largest quantities. Terpenes are also major constituents of Cannabis sativa plants, which contain at least 120 identified compounds. In addition to being responsible for the plant’s aroma, they can act synergistically with cannabinoids. In fact, there are several promising applications based on the combined use of cannabinoids and terpenes, such as new acne therapies utilizing CBD with the monoterpenes limonene, linalool, and pinene; new antiseptic agents with CBG and pinene; treatment of social anxiety disorder using CBD with limonene and linalool; and treatment of sleeping disorders by adding caryophyllene, linalool, and myrcene to 1:1 CBD/THC extracts.

Leer el artículo completo en Wikipedia · CC-BY-SA