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Meaning
  1. 1
    English · JMdict
    chemistry sulfurous acid;sulphurous acid
  2. 2
    English · Wikipedia

    Sulfurous acid (also sulphurous acid) is the chemical compound with the formula H2SO3. There is no evidence that sulfurous acid exists in solution, but the molecule has been detected in the gas phase. The conjugate bases of this elusive acid are, however, common anions, bisulfite (or hydrogen sulfite) and sulfite. Sulfurous acid is an intermediate species in the formation of acid rain from sulfur dioxide. Raman spectra of solutions of sulfur dioxide in water show only signals due to the SO2 molecule and the bisulfite ion, HSO−3. The intensities of the signals are consistent with the following equilibrium: SO2 + H2O ⇌ HSO−3 + H+ Ka = 1.54×10−2; pKa = 1.81. 17O NMR spectroscopy provided evidence that solutions of sulfurous acid and protonated sulfites contains a mixture of isomers, which is in equilibrium: [H–OSO2]− ⇌ [H–SO3]− When trying to concentrate the solution by evaporation to produce waterless sulfurous acid it will decompose (reversing the forming reaction). In cooling down a clathrate SO2 · 5,75 H2O will cristallize which decomposes again at 7 °C. Thus sulfurous acid H2SO3 cannot be isolated.

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